Remove the stems from the mushrooms and place them into a shallow dish or baking pan.
Add sesame oil, soy sauce, balsamic vinegar, tomato paste, liquid smoke, light brown sugar, crushed garlic, garlic powder, onion powder, salt and ground black pepper to a measuring jug and whisk together.
Brush the mushrooms generously with the marinade sauce on both sides and leave them to marinate for 15 minutes. Leave a little marinade sauce behind to use later.
Heat up a grill pan and brush it with ½ tablespoon of sesame oil. When the pan is hot add the mushrooms.
When the mushrooms first hit the pan they will stick, this is fine. After 3 minutes they should release on their own and have nice straight grill lines.
Grill the mushrooms for 3 minutes each side then turn off the heat and brush both sides of the mushrooms with marinade sauce.
Serve with roasted vegetables and baked potatoes or fries.